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Aromatic fluorine compounds as fungicides by G. C. Finger

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Published in Urbana .
Written in English


  • Fluorine.,
  • Fungicides.

Book details:

Edition Notes

Bibliography: p. 15.

Statementby G. C. Finger, Frank H. Reed, and Leo R. Tehon. A summary of cooperative research by the Illinois State Geological Survey, the Illinois State Natural History Survey, and the United States Air Force, 1950-1954.
LC ClassificationsQE105 .A45 no. 199
The Physical Object
Pagination15 p.
Number of Pages15
ID Numbers
Open LibraryOL209754M
LC Control Numbera 55009910

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  The book begins with a discussion of fluorine's unique combination of properties, including size, electronic effects, and hydrophobicity, as well as the historical development of its product applications. It explains methods for introducing fluorine into an aromatic ring, focusing on nucleophilic fluorine transfer reactions. Enter the password to open this PDF file: Cancel OK. File name: . Aromatic fluorine compounds as fungicides, By G.C. Finger, Frank H. Reed and Leo R. Tehon Download PDF (1 MB)Author: G.C. Finger, Frank H. Reed and Leo R. Tehon. Bibliography: p. Aromatic fluorine compounds as fungicides, Welcome to the IDEALS Repository. JavaScript is disabled for your browser. Some features of this site may not work without it.

  Aromatic hydrocarbon fungicides represent an older and chemically heterogeneous group of fungicides consisting of an aromatic ring system. They have been in use for a long time, but have lost their importance. Some of them are still valuable compounds in tropical countries and in use for controlling storage diseases. membrane permeation of the compound. 3. Increased binding affinity Fluorine substitution is being increasingly used to enhance the binding affinity of a compound to a target protein. This can occur by direct interaction of fluorine with the protein or indirectly by influencing the polarity of other groups of the compound which interact with. ( Å for fluorine versus Å for oxygen and Å for hydrogen).[18] Fluorinated compounds can be strategically used as transition state inhibitors.[2c] The high electronegativity of fluorine contributes to the high carbon–fluorine bond strength due to coulombic attraction between. Fluorinated compounds have shown efficacy as antibacterials, antifungicides, antibiotics, protease inhibitors and anticancer agents, among many other applications. Fluorinated compounds are widely used as fungicides, herbicides, and insecticides, and often show significantly more potency than their non-fluorinated analogues.

Nitration of mesitylene and difluoromesitylene in anhydrous hydrofluoric acid gave near quantitative yields of dinitromesitylene and 2,4-difluoronitromesitylene, respectively. Difluoro- and trifluoromesitylene were synthesized by the Schiemann reaction in record yields reported for this type of reaction. Various intermediates and derivatives are reported for the fluoromesitylenes. (1) are aromatic compounds bearing fluoro or trifluoromethyl substituents. Fluorinated aliphatic compounds are much less widely used as pharmaceuticals but two categories are important: steroids and anaesthetics (see Figure 3). Fluorinated steroids are exemplified by flumethasone. Fluorine-substitution in steroids. I would recommend this book to all scientists who consider working with fluorinated compounds-be they synthetic chemists, life-science chemists, or materials scientists." (Angewandte Chemie, ) "A wealth of information on the types of fluorinated heterocycles that are possible and their methods of synthesis, reactivity, and utilization. MNDO Parameters for the Prediction of 19F NMR Chemical Shifts in Biologically Relevant Compounds. The Journal of Physical Chemistry A , (37), DOI: /jpf. Norbert Lui,, Albrecht Marhold, and, Michael H. Rock.